She will smell different and be acting differenty after the spay, so he is curious. I would give her time to fully recover from the operation. When she is fully fit and able to deal with Harry's behaviour, you can give them supervised time together and see how it goes. So keep them separate for now so she can rest and heal for another week or so. He can still keep an eye on her and still have contact through a barrier, which will help to maintain the bond.
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